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Absolute configurations and rotations of exo- and endo-2-methylbicyclo[3.2.1]oct-3-ene

✍ Scribed by Goering, Harlan L.; Kantner, Steven S.


Book ID
120022647
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
609 KB
Volume
46
Category
Article
ISSN
0022-3263

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✍ G. Huybrechts; G. Ngoy πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 389 KB πŸ‘ 1 views

## Abstract The pyrolyses of endo‐ and exo‐5‐methylbicyclo (2.2.2) oct‐2‐ene (endo‐ and exo‐MBO) have been studied between 608 and 679Β°K at pressures between 7 and 37 torr. These reactions correspond to parallel first‐order eliminations of propene and ethylene: equation image The rate constants (