A μ-bis(phosphino)ethane gold(I) dimer
✍ Scribed by Schaefer, W. P. ;McCleskey, T. M. ;Gray, H. B.
- Book ID
- 114509201
- Publisher
- International Union of Crystallography
- Year
- 1992
- Tongue
- English
- Weight
- 331 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title compound, [Rh(C 26 H 24 ) 2 ](C 24 H 20 B), both the Rh and the B atom lie on twofold axes of symmetry. Selected geometrical parameters are Rh-P = 2.3076 (5) and 2.3114 (5) A ˚, and P-Rh-P = 82.43 (2) and 98.11 (2) .
The crystal structure of the title compound, [(dppe-P,P H )Cu-(dppeS-P)(SC{O}Ph)], [Cu(C 7 H 5 OS)(C 26 H 24 P 2 S)(C 26 H 24 P 2 )], is reported. In this monomeric compound, the Cu atom has a tetrahedral coordination geometry, with a P 3 CuS core.
In the title complex, [Au(C 26 H 48 P 2 ) 2 ]ClÁ4CHCl 3 , the cation and anion lie on twofold rotation axes. The Au atom has a distorted tetrahedral coordination geometry, with two chelating diphosphine ligands, and lies far from the anion.