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A Three-Dimensional Framework of Novel Vanadium Clusters Bridged by [Ni(en)2]2+: Ni(en)3{V11IVV5VO38Cl [Ni(en)2]3}×8.5H2O.

✍ Scribed by Cheng-Ling Pan; Ji-Qing Xu; Guang-Hua Li; De-Qing Chu; Tie-Gang Wang

Publisher
John Wiley and Sons
Year
2003
Weight
69 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract A new three‐dimensional zinc phosphite, Zn~3~(HPO~3~)~4~· Ni(en)~2~(H~2~O)~2~, which is the first example of an open‐framework metal phosphite templated by a transition‐metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO~4~ and HPO~3~ units re