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A Novel Open-Framework Zinc Phosphite, Zn3(HPO3)4·Ni(en)2(H2O)2, Templated by a Transition-Metal Complex

✍ Scribed by Zhi-En Lin; Jie Zhang; Shou-Tian Zheng; Guo-Yu Yang

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
161 KB
Volume
2004
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

A new three‐dimensional zinc phosphite, Zn~3~(HPO~3~)~4~· Ni(en)~2~(H~2~O)~2~, which is the first example of an open‐framework metal phosphite templated by a transition‐metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO~4~ and HPO~3~ units results in a three‐dimensional framework with intersecting 8‐ring and 12‐ring channels, in which the transition‐metal complexes reside. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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✍ Yu Song; Jihong Yu; Yi Li; Min Zhang; Ruren Xu 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB 👁 1 views

## Abstract By application of a combinatorial approach, a new open‐framework zinc phosphate [C~6~H~16~N~2~]·[Zn~2~(HPO~4~)~3~] (denoted as phase D) has been obtained in the Zn(OAc)~2~·2H~2~O/H~3~PO~4~/__N__,__N′__‐dimethylpiperazine/ethylene glycol solvothermal reaction system at 180 °C. The factor