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A Novel Open-Framework Zinc Phosphite, Zn3(HPO3)4×Ni(en)2 (H2O)2, Templated by a Transition-Metal Complex.

✍ Scribed by Zhi-En Lin; Jie Zhang; Shou-Tian Zheng; Guo-Yu Yang


Publisher
John Wiley and Sons
Year
2004
Weight
61 KB
Volume
35
Category
Article
ISSN
0931-7597

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A Novel Open-Framework Zinc Phosphite, Z
✍ Zhi-En Lin; Jie Zhang; Shou-Tian Zheng; Guo-Yu Yang 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 1 views

## Abstract A new three‐dimensional zinc phosphite, Zn~3~(HPO~3~)~4~· Ni(en)~2~(H~2~O)~2~, which is the first example of an open‐framework metal phosphite templated by a transition‐metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO~4~ and HPO~3~ units re

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## Abstract By application of a combinatorial approach, a new open‐framework zinc phosphate [C~6~H~16~N~2~]·[Zn~2~(HPO~4~)~3~] (denoted as phase D) has been obtained in the Zn(OAc)~2~·2H~2~O/H~3~PO~4~/__N__,__N′__‐dimethylpiperazine/ethylene glycol solvothermal reaction system at 180 °C. The factor