ChemInform Abstract: Hydrothermal Syntheses and Crystal Structures of Two New Mixed-Valence Vanadium Oxides [Ni(en)2(H2O)2] [Ni(en)3]2 [V16O38Cl]·3(H2O) and (H3O)2V3O8.
✍ Scribed by Xing Liu; Xian-Hong Yin; Feng Zhang
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 30 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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The first selenite chloride hydrates, Co(HSeO 3 )-Cl ´3 H 2 O and Cu(HSeO 3 )Cl ´2 H 2 O, have been prepared from solution and characterised by single-crystal X-ray diffraction. The cobalt phase adopts an unusual ªone-dimensionalº structure built up from vertex-sharing pyramidal [HSeO 3 ] 2± , and o