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A theoretical study of the Norrish type I reaction of acetone

✍ Scribed by Hideo Sakurai; Shigeki Kato

Book ID
114143335
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
202 KB
Volume
461-462
Category
Article
ISSN
0166-1280

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Femtochemistry of Norrish Type-I Reactio
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✍ Eric W.-G. Diau; Carsten KΓΆtting; Ahmed H. Zewail πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 531 KB

The dissociation dynamics of two acetone isotopomers ([D0 ]- and [D6 ]acetone) after 93 kcal mol(-1) (307 nm) excitation to the S1 (n,Ο€\*) state have been investigated using femtosecond pump-probe mass spectrometry. We found that the nuclear motions of the molecule on the S1 surface involve two time