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Femtochemistry of Norrish Type-I Reactions: IV. Highly Excited Ketones—Experimental

✍ Scribed by Theis I. Sølling; Eric W.-G. Diau; Carsten Kötting; Steven De Feyter; Ahmed H. Zewail


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
645 KB
Volume
3
Category
Article
ISSN
1439-4235

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Femtochemistry of Norrish Type-I Reactio
✍ Eric W.-G. Diau; Carsten Kötting; Ahmed H. Zewail 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The dissociation dynamics of two acetone isotopomers ([D0 ]- and [D6 ]acetone) after 93 kcal mol(-1) (307 nm) excitation to the S1 (n,π\*) state have been investigated using femtosecond pump-probe mass spectrometry. We found that the nuclear motions of the molecule on the S1 surface involve two time