Femtochemistry of Norrish Type-I Reactio
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Eric W.-G. Diau; Carsten Kötting; Ahmed H. Zewail
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Article
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2001
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John Wiley and Sons
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English
⚖ 531 KB
The dissociation dynamics of two acetone isotopomers ([D0 ]- and [D6 ]acetone) after 93 kcal mol(-1) (307 nm) excitation to the S1 (n,π\*) state have been investigated using femtosecond pump-probe mass spectrometry. We found that the nuclear motions of the molecule on the S1 surface involve two time