The dissociation dynamics of two acetone isotopomers ([D0 ]- and [D6 ]acetone) after 93 kcal mol(-1) (307 nm) excitation to the S1 (n,π\*) state have been investigated using femtosecond pump-probe mass spectrometry. We found that the nuclear motions of the molecule on the S1 surface involve two time
✦ LIBER ✦
Femtochemistry of Norrish Type-I Reactions: II. The Anomalous Predissociation Dynamics of Cyclobutanone on the S1 Surface
✍ Scribed by Eric W.-G. Diau; Carsten Kötting; Ahmed H. Zewail
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 313 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1439-4235
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## Quasiclassical trajectory calculations have been carried out for the reaction 0( 'D) +HD( 'Z\* )4OD/OH (%I) +H/D('S) using a two-valued potential energy surface derived by Murrell, Carter, Mills and Guest. The OD/OH branching ratio on this multivalued surface at 300 K is close to 2, and experim