✦ LIBER ✦
Quasiclassical dynamical study of the reaction O(1D)+HD(1Σ+)→OD/OH(2Π)+H/D(2S) on a two-valued potential energy surface
✍ Scribed by Lawrence J. Dunne
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 412 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Quasiclassical
trajectory calculations have been carried out for the reaction 0( 'D) +HD( 'Z* )4OD/OH (%I) +H/D('S) using a two-valued potential energy surface derived by Murrell, Carter, Mills and Guest. The OD/OH branching ratio on this multivalued surface at 300 K is close to 2, and experimental energy disposal data are well modelled using this potential.