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A two-photon study of the "reluctant" Norrish type I reaction of benzil

✍ Scribed by McGimpsey, W. G.; Scaiano, J. C.


Book ID
126438106
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
416 KB
Volume
109
Category
Article
ISSN
0002-7863

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The dissociation dynamics of two acetone isotopomers ([D0 ]- and [D6 ]acetone) after 93 kcal mol(-1) (307 nm) excitation to the S1 (n,Ο€\*) state have been investigated using femtosecond pump-probe mass spectrometry. We found that the nuclear motions of the molecule on the S1 surface involve two time