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Theoretical and experimental study of the Norrish I photodissociation of aromatic ketones

✍ Scribed by Dietlin, Céline; Allonas, Xavier; Defoin, Albert; Fouassier, Jean-Pierre

Book ID
120391412
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
376 KB
Volume
7
Category
Article
ISSN
1474-905X

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✍ Eric W.-G. Diau; Carsten Kötting; Ahmed H. Zewail 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The dissociation dynamics of two acetone isotopomers ([D0 ]- and [D6 ]acetone) after 93 kcal mol(-1) (307 nm) excitation to the S1 (n,π\*) state have been investigated using femtosecond pump-probe mass spectrometry. We found that the nuclear motions of the molecule on the S1 surface involve two time