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A study of the S(3P2,1,0; 1D2) production in the 193 nm photodissociation of HS and H2S

✍ Scribed by C.-W. Hsu; C.-L. Liao; Z.-X. Ma; P.J.H. Tjossem; C.Y. Ng


Book ID
107735331
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
619 KB
Volume
199
Category
Article
ISSN
0009-2614

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Photodissociation of H$ has been studied at 193.3 nm using H atom photofragment-translational speclroscopy with massspectrometric detection. H t HS( v) product branching ratios are reported which are not in quantitative agreement with other recent experimental results. Secondary photodissociation of

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Resonance-enhanced photoionization has been used to follow S(3P,) in the photodissociation of CS, at 193 nm. The contributions from initial photodissociation and from S('D) relaxation have been resolved and give a (15 f 5)X yield of S('D). The possibility of secondary production of S(3P,) by CS phot