The electrochemical reduction of Ti4 + ions in equimolar KCI-NaCl melts containing less K,TiFd (lwt %) on a Pt electrode, was studied at 973 K by means of linear sweep voltammetry, stationary current density-potential curve and ac impedance methods. It was found that the reduction of Ti4+ ions in th
A study of the electrochemical reduction of AlCl3 in an NaClKCl equimolar mixture
✍ Scribed by Jacques Bouteillon; Alain Marguier
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 467 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0376-4583
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Electrochemical Behavior of Magnesium Ions in the Equimolar CaCl2-NaCl Mixture at 550 • C. -Title studies performed by cyclic voltammetry, chronoamperometry, and chronopotentiometry show that Mg(II) and Mg(0) are the stable oxidation states of Mg in this mixture. The reduction of MgCl2 on a W electr
The cathodic reaction of the FeS, (pyrite) electrode in molten AICl,PNaCI electrolyte was studied by the nc impedance method. The faradaic components of the impedance for the FeS, electrode were considered to be the charge transfer, the surface reaction, and the diffusion processes. The faradaic imp
The polarographic reduction wave of magnesium ion was confirmed in the purified lithium chloride-potassium chloride eutectic + magnesium chloride (7.20 Y lo-' mol/l) melt kept at 450" C. The half wave potential was -2.53V us the Pt-Pt'+ reference electrode, which was very close to the equilibrium po
The Lux-Flood acid-base equilibrium SOS + o\*-+ so&%in molten equimolar NaCl/KCI at 750°C has been investigated using conventional chronopotentiometry. The equilibrium constant for this reaction is shown to be very high (K > 10"). Thus the sulphate ion in solution in this melt does not decompose unl