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ChemInform Abstract: Electrochemical Behavior of Magnesium Ions in the Equimolar CaCl2-NaCl Mixture at 550 °C.

✍ Scribed by Y. CASTRILLEJO; A. M. MARTINEZ; R. PARDO; G. M. HAARBERG

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199727013

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✦ Synopsis

Electrochemical Behavior of Magnesium Ions in the Equimolar CaCl2-NaCl Mixture at 550 • C. -Title studies performed by cyclic voltammetry, chronoamperometry, and chronopotentiometry show that Mg(II) and Mg(0) are the stable oxidation states of Mg in this mixture. The reduction of MgCl2 on a W electrode takes place in a single step and is quasireversible. Diffusion is the only mass transport mechanism of the Mg(II) species towards the electrode.

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