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A study of reaction conditions for the reaction of polybromobenzyl bromides and other benzyl bromides with metallic mercury

โœ Scribed by K. B. Butin; A. A. Ivkina; O. A. Reutov

Book ID
112442352
Publisher
Springer
Year
1985
Tongue
English
Weight
817 KB
Volume
34
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

Kinetics and mechanism of the reaction o
Kinetics and mechanism of the reaction of substituted benzyl bromides with copper in dimethylformamide
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The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k โ€ข ) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.24, S ฯ = 0.03, r = 0.

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## Abstract The reaction of copper with benzyl bromides in dipolar aprotic solvents has been studied. There are no linear or other simple relations between ฮต, 1/ฮต, __Y__, __P__, __n__, and the rate of reaction. The activity of the solvent is determined by donor number (DN) in reaction under conside

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