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ChemInform Abstract: A Novel Suzuki-Type Cross-Coupling Reaction of Cyclopropylboronic Esters with Benzyl Bromides.

✍ Scribed by Han Chen; Min-Zhi Deng

Publisher: John Wiley and Sons
Year: 2000
Weight: 29 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200040067

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A Novel Stereocontrolled Synthesis of Cyclopropyl-Substituted α,β-Unsaturated Esters: Palladium Catalyzed Cross-Coupling of Cyclopropylboronic Acids with Bromoacrylates. -Under optimized conditions A) trans-substituted cyclopropylboronic acids (I) react in a stereocontrolled manner with α,β-unsatur