The dynamics of the 193 nm laser-induced thermal desorption of NO monomer from an irradiated ClNO film held at 80 K has been studied using state-resolved laser-induced fluorescence of NO. The rotational and electronic (spin-orbit) populations of the desorbed NO( v=O) deduced from LIF excitation spec
A study of IR laser-induced desorption from benzene films by time-of-flight spectroscopy
โ Scribed by M. Buck; P. Hess
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 453 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
IR laser-induced desorption from benzene molecular films was studied by time-of-flight spectroscopy. Velocity distributions were measured as a function of laser wavelength, laser flucncc, film thickness and detection angle. The spectral dependence of the kinetic energy and the desorption yield follows the spectrum of the solid state, which differs considerably from the liquid state spectrum. This is consistent with a laser sublimation process. As in the case of other transient heating processes, a strong nonlinear fluence dependence of the desorption yield is observed.
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