A stereospecific synthesis of chiral 1,3-disubstituted bromoallenes
โ Scribed by E.J. Corey; Neil W. Boaz
- Book ID
- 107858351
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 241 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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A stereospecific synthesis of 23-difrcncdonalised terrahydrojiuans via a rransmetallation-alhylation sequence of the corresponding 2-(tri-bwyktannyl)tetmhydrofiuans is o&r&d.
The stereospecific synthesis of trans-1,3-disubstituted-1,2,3,4\_tetrahydro $-carbolines has been accomplished in good yield by a two step sequence which involves Pi&et-Spengler condensation of Nb-benzyltryptophan methyl: ester with aldehydes, followed by removal of the 2-benzyl moiety from the corr