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Stereochemistry of the sn2′ displacement of chiral 1, 3-disubstituted bromoallenes to form chiral acetylenes

✍ Scribed by E.J. Corey; Neil W. Boaz


Book ID
103398760
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
297 KB
Volume
25
Category
Article
ISSN
0040-4039

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Absolute stereochemistries of w-2,3-disubstituted spirocyclopropane-1,9'fluorene derivatives were determined by both CD and chemical transformation methods. In the CD-study, a stYry1 modification method for carboxyl substituted chiral centers is presented.