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A stereoselective formal synthesis of (±)-(γ)-lycorane

✍ Scribed by Steven R. Angle; Jim P. Boyce

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
246 KB
Volume
36
Category
Article
ISSN
0040-4039

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Lycorane has been synthesized in ten steps from of (+)-γ-lycorane was achieved via an optically active unsaturated aldehyde intermediate. piperonylic alcohol. Two radical reactions were used successively to build the D and B rings. A formal synthesis [a] Laboratoire de Chimie Organique, associe ´au

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A short synthesis of (+)-'/-lycorane is described featuring a radical cascade whereby rings B and D are formed in one step.