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An Efficient Palladium-Mediated Synthesis of (.+-.)-γ-Lycorane.

✍ Scribed by Zhihui Shao; Jingbo Chen; Rong Huang; Chenying Wang; Liang Li; Hongbin Zhang

Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Janine Cossy; Ludovic Tresnard; Domingo Gomez Pardo 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB 👁 1 views

Lycorane has been synthesized in ten steps from of (+)-γ-lycorane was achieved via an optically active unsaturated aldehyde intermediate. piperonylic alcohol. Two radical reactions were used successively to build the D and B rings. A formal synthesis [a] Laboratoire de Chimie Organique, associe ´au