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Efficient Synthesis of (.+-.)-γ-Lycorane Employing Stereoselective Conjugate Addition to Nitroolefin.

✍ Scribed by Tomohisa Yasuhara; Emi Osafune; Katsumi Nishimura; Mitsuaki Yamashita; Ken-ichi Yamada; Osamu Muraoka; Kiyoshi Tomioka


Publisher
John Wiley and Sons
Year
2004
Weight
134 KB
Volume
35
Category
Article
ISSN
0931-7597

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Stereoselective Conjugate Additions to γ
✍ Cristina Camarero; Ines Gonzalez-Temprano; Esther Lete; Nuria Sotomayor 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 39 KB

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Stereoselective Synthesis of Alcohols, X
✍ Hoffmann, Reinhard W. ;Kemper, Bruno ;Metternich, Rainer ;Lehmeier, Thomas 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 905 KB

Both the (Z)-and the (E)-y-alkoxy-substituted allylboronates 1 and 3 have been prepared. They add to aldehydes with a diastereoselectivity generally exceeding 90% to give the syn-(2) and anti-diol derivatives 4, respectively. The structure of one of these adducts has been established by conversion i