## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
✦ LIBER ✦
Efficient Synthesis of (.+-.)-γ-Lycorane Employing Stereoselective Conjugate Addition to Nitroolefin.
✍ Scribed by Tomohisa Yasuhara; Emi Osafune; Katsumi Nishimura; Mitsuaki Yamashita; Ken-ichi Yamada; Osamu Muraoka; Kiyoshi Tomioka
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 134 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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Both the (Z)-and the (E)-y-alkoxy-substituted allylboronates 1 and 3 have been prepared. They add to aldehydes with a diastereoselectivity generally exceeding 90% to give the syn-(2) and anti-diol derivatives 4, respectively. The structure of one of these adducts has been established by conversion i