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ChemInform Abstract: Organocatalytic Enantioselective Conjugate Addition of 2-Fluoromalonate to Nitroolefins: Direct Synthesis of Chiral Fluorinated γ-Nitro Carboxylic Acid Derivatives.

✍ Scribed by Hao Li; Liansuo Zu; Hexin Xie; Wei Wang

Publisher
John Wiley and Sons
Year
2009
Weight
32 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract The configuration of the olefins has significant influence on the stereoselectivity: the (Z)‐isomer provides the highest yield and enantioselectivity, while the (E)‐isomer or the Z/E‐mixture afford poor results.