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ChemInform Abstract: Enantioselective Conjugate Addition of Oximes to Trisubstituted β-Nitroacrylates: An Organocatalytic Approach to β2,2-Amino Acid Derivatives.

✍ Scribed by Fu-Gen Zhang; Qing-Qing Yang; Jun Xuan; Hai-Hua Lu; Shu-Wen Duan; Jia-Rong Chen; Wen-Jing Xiao

Publisher
John Wiley and Sons
Year
2011
Weight
53 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The configuration of the olefins has significant influence on the stereoselectivity: the (Z)‐isomer provides the highest yield and enantioselectivity, while the (E)‐isomer or the Z/E‐mixture afford poor results.

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