A Stereochemically Well-Defined Rhodium(III) Catalyst for Asymmetric Transfer Hydrogenation of Ketones.
β Scribed by Daljit S. Matharu; David J. Morris; Aparecida M. Kawamoto; Guy J. Clarkson; Martin Wills
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 27 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Tridentate __N,N,N__βpyridinebisimidazolines have been studied as new ligands for the enantioselective transfer hydrogenation of prochiral ketones. High yields and excellent enantioselectivity up to >99β% __ee__ have been achieved with an __in situ__ generated catalytic system containin