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An Efficient Ir(III) Catalyst for the Asymmetric Transfer Hydrogenation of Ketones in Neat Water.

✍ Scribed by Xiaohong Li; John Blacker; Ian Houson; Xiaofeng Wu; Jianliang Xiao

Publisher
John Wiley and Sons
Year
2006
Weight
23 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Polyethylene glycol-bound Ru catalyst fo
Polyethylene glycol-bound Ru catalyst for asymmetric transfer hydrogenation of aromatic ketones in water
✍ Zhongqiang Zhou; Qiong Ma πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 113 KB πŸ‘ 1 views

## Abstract A new polyethylene glycol‐supported chiral monosulfonamide was synthesized from (__R__,__R__)‐1,2‐diaminocyclohexane and shown to act as a ligand for ruthenium(II)‐catalyzed asymmetric transfer hydrogenation of aromatic ketones in neat water using sodium formate as the hydrogen source.