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New Ruthenium Catalysts for Asymmetric Transfer Hydrogenation of Prochiral Ketones.

✍ Scribed by Stephan Enthaler; Bernhard Hagemann; Santosh Bhor; Gopinathan Anilkumar; Man Kin Tse; Bianca Bitterlich; Kathrin Junge; Giulia Erre; Matthias Beller


Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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New Ruthenium Catalysts for Asymmetric T
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## Abstract Tridentate __N,N,N__‐pyridinebisimidazolines have been studied as new ligands for the enantioselective transfer hydrogenation of prochiral ketones. High yields and excellent enantioselectivity up to >99 % __ee__ have been achieved with an __in situ__ generated catalytic system containin

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