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A Simple Synthesis of [(Cp*Al)4] and Its Conversion to the Heterocubanes [(Cp*AlSe)4] and [(Cp*AlTe)4] (Cp* = η5-C5(CH3)5)

✍ Scribed by Dipl.-Chem. Stephan Schulz; Prof. Dr. Herbert W. Roesky; Dr. Hans Joachim Koch; Prof. George M. Sheldrick; Dr. Dietmar Stalke; Annja Kuhn


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
405 KB
Volume
32
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Eine einfache Synthese von [(Cp*Al)4] un
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H,SO, bis pH 2 angcsiuert. Der sofort ausfallendc wciOc. rosa schimmernde Niederschlag wird mit 10 mbar uber eine Glasfritte abgesaugt. drei ma1 mit 25 mL Eiswasser uud dreimal mit 25 mL n-Hexan gewaschen und 3 h bei 5 x mbar getrocknet. Ausb. 0.25 g (1.2 mmol, 57%) mil Schmp. 93°C (Zers.

Cp′2TiS5O and Cp′2TiOS5—Isomeric Titanoc
✍ Prof. Dr. Ralf Steudel; Dipl.-Chem. Andreas Prenzel; Prof. Dr. Joachim Pickardt 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 371 KB 👁 2 views

varied iteratively in the refinement until an equivalent isotropic displacement factor comparable with that at the other positions resulted. For each ring position in the disorder model so obtained the C:P ratio was fixed, an anisotropic displacement factor refined together with the atomic positions