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Structural and Magnetic Studies of the Tris(cyclopentadienyl)manganese(II) “Paddle-Wheel” Anions [Cp3−n(MeCp)nMn]− (n=0–3, MeCp=C5H4CH3, Cp=C5H5)

✍ Scribed by Carmen Soria Alvarez; Alan Bashall; Eric J. L. McInnes; Richard A. Layfield; Richard A. Mole; Mary McPartlin; Jeremy M. Rawson; Paul T. Wood; Dominic S. Wright


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
234 KB
Volume
12
Category
Article
ISSN
0947-6539

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Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged