Isomerization of the cationic complex of the type Coen?Xi (X-= singly charged anionic ligand) in basic solution proceeds through ion-pair formation [l], The, study of isomerization of the present anionic complex was undertaken as with this complex, ion-pair formation is untenable and isomerization m
A simple solvent model for electron transfer reactions.
โ Scribed by Maurizio Cossi; Maurizio Persico; Jacopo Tomasi
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 808 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0167-7322
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๐ SIMILAR VOLUMES
Electron and ion transfer reactions on metal electrodes are considered in an extended Anderson model, in which the interactions of the reactant with the metal and with the solvent depend on the separation from the interface. The model allows the construction of effective potential energy surfaces. E
## Solvent effects in simple electron transfer reactions are reviewed. It is shown that estimation of the outer sphere Gibbs activation energy is often difficult. Data for the electroreduction of Fe(H20):+ at single crystal gold electrodes are also discussed. This system shows a very large double