𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A unified model for electrochemical electron and ion transfer reactions

✍ Scribed by Wolfgang Schmickler

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
674 KB
Volume
237
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Electron and ion transfer reactions on metal electrodes are considered in an extended Anderson model, in which the interactions of the reactant with the metal and with the solvent depend on the separation from the interface. The model allows the construction of effective potential energy surfaces. Explicit calculations are performed for the transfer of an iodide ion and for the electron transfer reaction of the Fe2+/Fe 3+ couple.

πŸ“œ SIMILAR VOLUMES

Superexchange electron-transfer reaction
Superexchange electron-transfer reactions in a three-component system. The spin-boson model for photosynthesis
✍ Jau Tang πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 476 KB

The rate expression for the superexchange reaction in a three-component system, involving a donor, a bridging intermediate and a distant acceptor, is derived using the spin-boson model for the primary electron transfer in a photosynthetic reaction center. In this model, a vector spin for SU( 3) grou

Role of the solvent in the kinetics of h
Role of the solvent in the kinetics of heterogeneous electron and ion transfer reactions
✍ W.Ronald Fawcett; Colby A. Foss Jr πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 900 KB

## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can