Electron and ion transfer reactions on metal electrodes are considered in an extended Anderson model, in which the interactions of the reactant with the metal and with the solvent depend on the separation from the interface. The model allows the construction of effective potential energy surfaces. E
โฆ LIBER โฆ
A Pressure- and Temperature-Controlled Electrochemical Cell for Investigating Biological Electron Transfer Reactions
โ Scribed by E.T. Smith
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 635 KB
- Volume
- 224
- Category
- Article
- ISSN
- 0003-2697
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A three electrode thin-layer, ยฏow-by electrode cell was coupled on-line with electrospray-mass spectrometry (i.e., ECaES-MS) for the study of biological redox reactions. The cell made use of a commercially available 6.0 mm diameter, offset glassy carbon disk working electrode, a AgaAgCl reference el