## Receivd 1 March 1976 The possibility of electron-transfer (ET) biradiul formation in the ground state is investigated in relation to the oneelectron transfer mechanism in so-called ionic reactions. The difference between the electronic properties of ET and homolytic biradiuls is also discussed
โฆ LIBER โฆ
A general model for electron-transfer reactions via electronic intermediate states
โ Scribed by Wolfgang Schmickler
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 399 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0022-0728
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Electron and ion transfer reactions on metal electrodes are considered in an extended Anderson model, in which the interactions of the reactant with the metal and with the solvent depend on the separation from the interface. The model allows the construction of effective potential energy surfaces. E