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Electron-transfer biradical intermediates in ground-state reactions

✍ Scribed by Teruhiro Takabe; Kizashi Yamaguchi

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
514 KB
Volume
40
Category
Article
ISSN
0009-2614

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✦ Synopsis

Receivd 1 March 1976

The possibility of electron-transfer (ET) biradiul formation in the ground state is investigated in relation to the oneelectron transfer mechanism in so-called ionic reactions. The difference between the electronic properties of ET and homolytic biradiuls is also discussed on the basis of the molecular orbital and intermolecular configuration interaction methods.

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parameters was carried out by the method of least squares with anisotropic temperature factors. After the final cycle including all observed F(hkl) the factor R had a value 0.10. X-ray crystallographic investigation showed, that the previously unobserved structure of a dicubane is in fact present. T