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A simple and practical synthesis of α-trifluoromethylated alcohols in water

✍ Scribed by Teck-Peng Loh; Xu-Ran Li

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 635 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00227-6

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✦ Synopsis

A simple and practical preparation of a-trifluoromethylated alcohols in water v/a indium-mediated allylation reaction and tin-mediated indium trichloride-promoted ailylation reaction of trifluoroacetaldehyde hydrate and its ethyl hcmiacetal is described in this paper.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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1,1-Trifluoro-4-bromobut-2-ene / Aldehydes / Tin / Indium / Water The indium-mediated allylation reaction of aldehydes with 4-high regio-and excellent diastereoselectivities were obtained. bromo-1,1,1-trifluoro-2-butene in water afforded β-trifluoromethylated homoallylic alcohols in high yields. In