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ChemInform Abstract: A Highly Stereoselective Synthesis of β-Trifluoromethylated Homoallylic Alcohols in Water.

✍ Scribed by T.-P. LOH; X.-R. LI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Tin- and Indium-Mediated Allylation Reac
Tin- and Indium-Mediated Allylation Reactions in Water: Highly Stereoselective Synthesis of β-Trifluoromethylated Homoallylic Alcohols
✍ Teck-Peng Loh; Xu-Ran Li 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 249 KB 👁 2 views

1,1-Trifluoro-4-bromobut-2-ene / Aldehydes / Tin / Indium / Water The indium-mediated allylation reaction of aldehydes with 4-high regio-and excellent diastereoselectivities were obtained. bromo-1,1,1-trifluoro-2-butene in water afforded β-trifluoromethylated homoallylic alcohols in high yields. In