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A Practical Asymmetric Synthesis of Isopropyl (1 R ,2 S )-Dehydrocoronamate

โœ Scribed by Tang, Wenjun; Wei, Xudong; Yee, Nathan K.; Patel, Nitinchandra; Lee, Heewon; Savoie, Jolaine; Senanayake, Chris H.


Book ID
118019329
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
924 KB
Volume
15
Category
Article
ISSN
1083-6160

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A practical new asymmetric synthesis of
โœ Karl J. Hale; Soraya Manaviazar; Vern M. Delisser ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 552 KB

Abstmctz A convenient new asymmetric synthesis of both enaatiomcrs of eryrhro-3-hydroxylcuciae is desctibed. The key steps involve Sharpless asymmetric dihydroxylation (AD) of a&unsaturated ester 3, cyclic sulphate formation from the resulting diol, SNZ reaction with sodium azide, deesterification w