A novel reaction of nitric acid with steroids
โ Scribed by C.R. Narayanan; M.S. Parker; M.S. Wadia
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 189 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Reaction of nitric acid vlth unsaturated steroids under mild conditions Is known for a very long time and several authors have carried aut this reaction to prepare nltrosterolds l-3. In aw hands this reaction yielded a novel pro&et whose structure and mode of formation Is now elucidated.
๐ SIMILAR VOLUMES
## THE PREBIDENT. If han boon an invariable practioo that tho h s i d c n t of tho Royal Society should hold no similar ofioo in othor I c a m f ~c t i e a , and in creconlence with this well rcc0-d rulo Sir Wm. h k c e hen reluctantly felt compelled to re-tho PrCMlenoy of tho h i e t of Chemical
Recently-described work1 on the ene-reaction between acrylonitrile and ergosteryl acetate to give the adducts (I-III) leads us to report our investigation of some unusual reactions of tetracyanoethylene with three steroidal cisoid dienes. Tetracysnoethylene reacted rapidly with ergosteryl acetate in