Reaction of nitric acid vlth unsaturated steroids under mild conditions Is known for a very long time and several authors have carried aut this reaction to prepare nltrosterolds l-3. In aw hands this reaction yielded a novel pro&et whose structure and mode of formation Is now elucidated.
Steroids XII a novel addition reaction of mercuric salts with unsaturated steroidal ketones
✍ Scribed by M. Kocór; M. Gumulka
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 173 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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We have been interested' in the study of the reactivity of 17~4\_, 20;20,21-bismethylenedioxy-l9-norpregns-l,3,5(10),9(l1~ -tetraen-3-yl methyl ether(I)\* In the present communication we wish to report an unusual reaotion aourse Of(l) with I-bromsuco$ni&de, When (I) was refluxed with NBS in CC14 sol
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