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Novel ene- reactions of tetracyanoethylene with steroidal dienes

✍ Scribed by Anne M. Lautzenheiser; P.W. LeQuesne

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
193 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recently-described work1 on the ene-reaction between acrylonitrile and ergosteryl acetate to give the adducts (I-III) leads us to report our investigation of some unusual reactions of tetracyanoethylene with three steroidal cisoid dienes. Tetracysnoethylene reacted rapidly with ergosteryl acetate in benzene solution to give a 1:l adduct, C H N 0 36 46 4 2,** m.p. 135", [al, 25 -170" in

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