Halogenation of thiocarboxylic acid 0-silyl esters gave acylsulfenyl halides in high yields, involving a thiophilic attack of halogen ion on the sulfur atom of thiocarbonyl group. Aliphatic acylsulfenyl bromide was isolated for the first time. In spite of the easy availability of thiocarboxylic aci
A novel method to synthesize O-esters of thiocarboxylic acids
โ Scribed by A. Ohno; T. Koizumi; G. Tsuchihashi
- Book ID
- 104222937
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 169 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Esters of thiocarboxylic O-acids have previously been prepared by the reaction of imido ethers (Ia> with hydrogen sulfide, or by the reaction of Grignard reagents with chlorothiocarbonic acid O-esters (Ib) (l-4). An alternative method involves the reaction of immonium-type salts (II) with hydrogen &NH S X R-C ' GR' Cl-CC R-b=fi/ B' + -
๐ SIMILAR VOLUMES
## Abstract A novel method suitable for the synthesis of the cobalt oxide (Co~3~O~4~) nanowires at targeted regions is presented in this report. Cobalt (Co) nanobowls synthesized by colloidal crystal directed assembly were transformed into Co~3~O~4~ nanowires by a simple heat treatment process. Co