✦ LIBER ✦

Thiophilic halogenation of thiocarboxylic acid O-silyl esters. A facile preparation of acylsulfenyl halides

✍ Scribed by Toshiaki Murai; Shigeru Oida; Shi Min; Shinzi Kato

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 121 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85012-1

No coin nor oath required. For personal study only.

✦ Synopsis

Halogenation of thiocarboxylic acid 0-silyl esters gave acylsulfenyl halides in high yields, involving a thiophilic attack of halogen ion on the sulfur atom of thiocarbonyl group. Aliphatic acylsulfenyl bromide was isolated for the first time.

In spite of the easy availability of thiocarboxylic acid O-esters, relatively little attention has been received on these compounds.

📜 SIMILAR VOLUMES

Facile and Selective Preparation of Este

Facile and Selective Preparation of Esters from Carboxylic Acids Catalyzed by Aluminumdodecatangstophosphate (AlWP12O40) as a Versatile, Recyclable and a Highly Water Tolerant Green Lewis Acid Catalyst.

✍ Habib Friouzabadi; Nasser Iranpoor; Abbas Ali Jafari 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.