A new synthesis of π-electron conjugated phosphonates and phosphonic bis(diethylamides) and their SHG activities
✍ Scribed by Ogawa, Takuji; Usuki, Naoya; Ono, Noboru
- Book ID
- 111677894
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Weight
- 153 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1472-7781
- DOI
- 10.1039/a709082j
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A new Wadsworth-Emmons reagent, tetrakis(2,2,2-trifluoroethyl) methylenediphosphonate, was prepared and its reaction with aldehydes to yield (Z)-vinyl phosphonates is described. Additionally, an example of a base catalyzed isomerization ofa (Z)-vinyl phosphonate to the corresponding (E)-allylic phos
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