𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new synthesis of nitriles

✍ Scribed by Takahiro Saraie; Toshihiro Ishiguro; ]Kenya Kawashima; Katsura Morita


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
139 KB
Volume
14
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


The dehydration of amides or aldoximes to yield nltriles generally requires Lewis acids and vigorous reaction conditions, which prevent one from applying the method to thermally labile nitriles.

Recently sane efforts have been made to achieve the dehydratlon under milder conditions. For example, amldes and aldoximes were dehydrated


πŸ“œ SIMILAR VOLUMES


A new synthesis of nitriles
✍ W. Brackman; P. J. Smit πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 250 KB

## Abstract Nitriles can be obtained in good yields (60‐80%) by treatment with oxygen at 30Β° of a methanolic solution of the corresponding aldehyde, containing ammonia, a strong base and a catalytically active copper complex. Yields are lower for base‐sensitive aldehydes. In a similar way, but in

Synthesis of 3-imidazolylazole derivativ
✍ Francesco Foti; Giovanni Grassi; Francesco Risitano; Salvatore La Rosa πŸ“‚ Article πŸ“… 2001 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 24 KB

## Abstract The synthesis of a series of 3‐Imidazolylazole derivatives using cycloaddition reactions of a useful new nitrile oxide is described.

Intramolecular cyclization of a dieno-ni
✍ Yasuo Butsugan; Shigeo Yoshida; Masao Muto; Tadaaki Bito; Teruo Matsuura; Ruka N πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 94 KB

We wish to report an intramolecular cyclisation between nitrile and conjugated diene moieties leading to a monoterpene alkaloid with a pyridine nucleus. Rose bengal-sesitized photooxygenation of (-)-citronellonitrile' (&) in methanol followed by reduction of the