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Intramolecular cyclization of a dieno-nitrile: synthesis of a new monoterpene alkaloid

✍ Scribed by Yasuo Butsugan; Shigeo Yoshida; Masao Muto; Tadaaki Bito; Teruo Matsuura; Ruka Nakashima

Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 94 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)96645-6

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✦ Synopsis

We wish to report an intramolecular cyclisation between nitrile and conjugated diene moieties leading to a monoterpene alkaloid with a pyridine nucleus. Rose bengal-sesitized photooxygenation of (-)-citronellonitrile' (&) in methanol followed by reduction of the

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