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A new stereoselective synthesis of dl-pumiliotoxin C using novel 1,3-bis(trimethylsilyloxy)-1,3-dienes

✍ Scribed by Toshiro Ibuka; Yuji Mori; Yasuo Inubushi


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
210 KB
Volume
17
Category
Article
ISSN
0040-4039

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Functionalized benzo[c] phenanthrenes ([4]helicenes) and [5]helicenes were synthesised in five steps from tetrahydronaphthalenone and tetrahydrophenanthrenone compounds using a novel synthetic approach based on a Diels-Alder reaction between inner-outer ring 1,3-bis(trimethylsilyloxy)-1,3-dienes an