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Synthesis of polycyclic structures by Diels-Alder reaction using inner-outer-ring 1,3-bis[trimethylsilyloxy]dienes

✍ Scribed by José Pérez Sestelo; Madel Mar Real; Antonio Mouriño; Luis A. Sarandeses


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
224 KB
Volume
40
Category
Article
ISSN
0040-4039

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Inner–outer ring 1,3-bis(trimethylsilylo
✍ Ma̱ del Mar Real; José Pérez Sestelo; Luis A. Sarandeses 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 110 KB

Functionalized benzo[c] phenanthrenes ([4]helicenes) and [5]helicenes were synthesised in five steps from tetrahydronaphthalenone and tetrahydrophenanthrenone compounds using a novel synthetic approach based on a Diels-Alder reaction between inner-outer ring 1,3-bis(trimethylsilyloxy)-1,3-dienes an