Acylation of the readily available 3-methyl-3-hydroxymethyl oxetane Q leads to the corresponding oxetane esters (3 which rearrange smoothly in the presence of boron trifluoride etherate in methylene chloride at -15" to form ortho esters of the 2,6,7-trioxabicyclo[2.2. aloctane series (2). Protectio
β¦ LIBER β¦
A new general synthetic route to bridged carboxylic ortho esters
β Scribed by E.J. Corey; Natarajan Raju
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 216 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
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