New synthetic route to carboxylic esters from grignard reagents
โ Scribed by Masakazu Yamashita; Rikisaku Suemitsu
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 96 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Acylation of the readily available 3-methyl-3-hydroxymethyl oxetane Q leads to the corresponding oxetane esters (3 which rearrange smoothly in the presence of boron trifluoride etherate in methylene chloride at -15" to form ortho esters of the 2,6,7-trioxabicyclo[2.2. aloctane series (2). Protectio
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Dialkyl arylphosphate esters have been synthesized in improved yields by the reaction of dicyclohexylamine salts of substituted phenols with dialkyl hydrogen phosphite and carbon tetrachloride. The reaction proceeds through the corresponding phosphorochloridates. Dialkyl arylphosphate esters form a
A general method for preparing (arylalkenyl)siianes via nucleophilic capture of arynes with vinyltrimethylsilyl Grtgnard reagents is described. We recently developed methodology for forming from one to four new aryl-carbon bonds in a one-pot reaction by treating various polyhalobenzenes with aryll